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REG - Castillo Copper Ltd - NWQ Copper Project’s development targets

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RNS Number : 4719N  Castillo Copper Limited  23 January 2023

23 January 2023

 

 

CASTILLO COPPER LIMITED

("Castillo", or the "Company")

 

 

NWQ Copper Project's development targets

 

Castillo Copper Limited (LSE and ASX: CCZ), a base metal explorer primarily
focused on copper across Australia and Zambia, announces that following a
review of prospects within the NWQ Copper Project (Appendix A), has authorised
the geology team to visit several prospects - including Big One, Arya and
Valparaisa - during 1H 2023 to identify new targets for test-drilling.

 

HIGHLIGHTS:

 

·    Initial focus will be on the Big One, which has an inferred Mineral
Resource Estimate (MRE) of 2.1Mt @ 1.1% Cu for 21,886kt(1) copper metal
post-two drilling campaigns across 2020-21:

o  Factoring in a large conductor north of the line of lode, plus reconciling
available geophysics and geochemical data, Castillo's geological consultant
has set an Exploration Target that ranges from 2-6Mt @ 0.6-1% Cu for 12-60kt
copper metal*

·    The Valparaisa Prospect comprises copper mineralisation across two
horizons over a 6km strike event, with the interaction of two intersecting
faults suggesting a structurally controlled copper system that can potentially
be drill-tested(2)

·    At the Arya Prospect, there is a significant magnetic anomaly, south
of a known graphite system(3) (test drilled in late 2021), that shows
potential to be a primary source of copper mineralisation

·    Meanwhile, final drill and auger assays, which are still pending,
should define the potential scale of the rare earth element discovery at the
BHA Project's East Zone

 

 

Dr Dennis Jensen, Managing Director of Castillo Copper, said: "With the
macro-outlook for copper remaining upbeat, the Board has authorised the
geology team to visit several prospects to identify new targets to test-drill.
Key areas of focus include increasing the grade and confidence in the current
MRE at Big One and the magnetic anomaly at the Arya Prospect. Given the large
size of the NWQ Copper Project, the Board remains open to aligning with a
strategic partner to further advance development work."

 

* Cautionary Statement: It should be noted that the Exploration Target tonnage
range quoted above are conceptual in nature and there has been insufficient
exploration to define a copper resource.  Although a preliminary analysis was
undertaken, insufficient data exists to confidently correlate mineralised
horizons within the Exploration Target area. It is uncertain whether further
exploration may lead to the reporting of a JORC-standard resource, however,
there is some evidence to support the current exploration tonnage
calculations, and the sufficient mineralised thicknesses interpreted from
historical drilling to warrant further investigation in some areas.

 

 

 

NWQ Copper Project - Site Visit

 

A summary of salient points from the review for the three prospects
highlighted follows:

 

Big One

 

Whilst some areas around Big One were drill-tested in the 2020-21 drilling
campaigns, much of the area remains under-explored which highlights the
exploration potential.

 

Utilising information from Castillo's drilling campaigns, complemented with
historical data, Castillo's geological consultant compiled an extensive
database, built a block model, and produced a maiden 2012 JORC Inferred MRE at
2.1Mt @ 1.1% Cu for 21,886kt copper metal(1) (Figure 1).

 

FIGURE 1:  MINERAL RESOURCE TONNAGES BIG ONE COPPER MINE

 

 Tenure Name  Ore Type  Depth (m)       Specific Gravity (kg/m(3))  Inferred (Mt)  Indicated (Mt)  Copper Grade %  Silver Grade  Contained Copper (t)  Contained

                                                                                                                   g/t                                 Silver (kg)
 Mine Dumps   Oxidised  At surface/ROM  2.55                        0              0.007           1.2             4.0           86                    29.6
 Mine Insitu  Oxidised  2-70            2.65                        1.7            0               1.0             1.1           17,000                1,870
 Mine Insitu  Fresh     70-120          2.75                        0.4            0               1.2             1.4           4,800                 560
 Sub-Totals                                                         2.1            0.007                                         21,886                2,459.6

Note: No measured resources estimated

Source: CCZ geology team

Building on this work, the geology team believe further drilling is warranted
along the known orebody to the east, north and downdip as it is not fully
defined. Specifically, the geology team believe a well-designed drilling
campaign - focussing on diamond coring - has the potential to materially
increase the grade and confidence in the current MRE, as the orebody is open
to the east and downdip.

 

In addition, an Exploration Target* (to the standard of Clause 17 of the 2012
JORC Code) has been estimated utilising the following information:

·    the MRE plus some areas proximal to and downdip to the main resource
shell; and

·    available geophysics and surface sampling data.

 

The Exploration Target's* mid-range is 4Mt @ 0.6-1.0% Cu, with the low at 2Mt
and high at 6Mt - refer to Figures 2 and 3. It should be explained that this
is an enlarged range of tonnage compared to the MRE due a new wireframe model
extended along the entire line of lode.

 

* Cautionary Statement: It should be noted that the Exploration Target tonnage
range quoted above are conceptual in nature and there has been insufficient
exploration to define a copper resource.  Although a preliminary analysis was
undertaken, insufficient data exists to confidently correlate mineralised
horizons within the Exploration Target area.  It is uncertain whether further
exploration may lead to the reporting of a JORC-standard resource however
there is some evidence to support the current exploration tonnage
calculations, and the sufficient mineralised thicknesses interpreted from
historical drilling to warrant further investigation in some areas.

 

 

FIGURE 2:  BIG ONE - EXPLORATION TARGET *

 Target   Strike Length (m)  Strike Length (m)  Width (m)  Width (m)  Depth below surface (m)  Depth below surface (m)  Density (t/m(3))  Density (t/m(3))
 Ranges   Low                High               Low        High       Low                      High                     Low               High
 Big One  600                1,550              4          14         10                       190                      2.65              2.80

Note: Mid-points as follows - Strike length (1,550m); Width (9m); Depth below
surface (100m); Density (2.725t/m3)

Source: CCZ geology team

FIGURE 3:  BIG ONE - EXPLORATION TARGET FOR COPPER *

 Target   Tonnage (Mt)  Tonnage (Mt)  Grade (%)  Grade (%)  Contained Cu (t)  Contained Cu (t)
 Ranges   Low           High          Low        High       Low               High
 Big One  2.0           6.0           0.6        1.0        12,000            60,000

Note:

1.        Mid-points as follows - Tonnage (4Mt); Grade (0.8%);
Contained copper (32,000t)

2.        Volume and mass are exclusive of the Big One Copper Mine's
Inferred resource shell.

3.        Where quoted, it should be noted that where Exploration
Target tonnages are estimated in this ASX Release, they are considered
non-JORC (Clause 17 Exploration Results) and are conceptual in nature.  There
has been insufficient exploration to define a Mineral Resource and that it is
uncertain if further exploration will result in the determination of a Mineral
Resource.

4.        At 0.5% Cu cut-off.

Source: CCZ geology team

 

* Cautionary Statement: It should be noted that the Exploration Target tonnage
range quoted above are conceptual in nature and there has been insufficient
exploration to define a copper resource.  Although a preliminary analysis was
undertaken, insufficient data exists to confidently correlate mineralised
horizons within the Exploration Target area.  It is uncertain whether further
exploration may lead to the reporting of a JORC-standard resource however
there is some evidence to support the current exploration tonnage
calculations, and the sufficient mineralised thicknesses interpreted from
historical drilling to warrant further investigation in some areas.

 

 

Valparaisa Prospect

The Valparaisa Prospect comprises copper mineralisation in two horizons -
termed the "upper and lower copper beds" - within the Middle Gunpowder Creek
Formation over a 6km strike length (Figure 4). Compared with the 'upper bed'
the 'lower bed' has the stronger outcrop and more copper staining(2).

 

Previous explorers, including BHP, undertook rock-chip sampling which returned
high-grade assay results up to 2,530ppm Cu, demonstrating prospectivity at
surface for copper mineralisation(2). Interestingly, the surface anomalism
aligns with the interaction of two intersecting faults - Mt Gordon (SW-NE -
links to Mt Mammoth Deposit) and Valparaisa (SSE-NNW).

 

Reconciling and interpreting the foregoing facts has postulated that there is
a structurally controlled copper system at the Valparaisa Prospect.

 

FIGURE 4: VALPARAISA PROSPECT - SOLID GEOLOGY, ROCK CHIPS & DRILLHOLES

Source: CCZ geology team

In terms of identifying potential targets for closer scrutiny, a key positive
was identifying the Whitworth Quartzite rock formation within the Valparaisa
fault. This is significant as it hosts copper sulphide mineralisation within
the Mt Gordon fault at the Mt Mammoth Deposit. Reconciling this against
overlaid magnetic imagery, enables several target areas for structurally
controlled copper and supergene ore mineralisation to be generated (Figure
5).

 

 

FIGURE 5: STRUCTURALLY CONTROLLED AND SUPERGENE TARGETS

Source: CCZ geology team

Arya Prospect

A limited drilling campaign in late 2021, designed to test several large
airborne electro-magnetic and ground resistivity anomalies, confirmed a
low-grade graphite system that won't be further explored (refer Appendix B for
assay results).

 

However, a sizeable magnetic anomaly - south of the known electro-magnetic
anomalies - is interpreted to be associated with known surface copper and to a
lesser degree silver mineralisation. A key focus of the site visit is to
determine if this should be drill-tested as it may be a primary source of base
metal mineralisation at the Arya Prospect.

 

In terms of regional geology, the Arya Prospect is located in the Western Mt
Isa Succession, within a structurally deformed and copper anomalous district
that hosts the Capricorn Copper Mine, Mt Oxide Mine and the Ladie Annie Mine.
These are hosted within units of the upper Myally sub-group to lower McNamara
Group, while the Arya Prospect is hosted within the Surprise Creek formation
(Figure 6).

 

FIGURE 6: STRATIGRAPHIC COLUMN

Source: Smith (2019) - reference 4

In terms of local geology, the Arya Prospect is located within the Surprise
Creek Formation unit (Prd), with several results from rock-chip sampling
indicative of a structural system for anomalous copper values (Figure 7).
Moreover, the Arya Prospect is proximal to an east to north-east trending
fault that offsets the Surprise Creek unit (Prd) from lower units near the
base of the Surprise Creek Formation, and Myally Sub-Group units, including
quartzites, and sandstones.

 

FIGURE 7: COPPER GEOCHEMISTRY ON QUEENSLAND GOVT GEOLOGICAL MAP

Source: Smith (2019) - reference 4

Interpreting these findings, suggests probable mineralisation styles include:

·    Supergene mineralisation forming at the surface along the fault,
fault breccia, and the Surprise Creek Formation (PLrd) rock unit.

·    Epigenetic replacement mineralisation for Cu (with minor components
of other base metals and gold) from replacement carbonate mineralisation,
particularly the Surprise Creek Formation.

·    Skarn mineralisation for Cu-Au and/or Zn-Pb-Cu from replacement
carbonate mineralisation, particularly the Surprised Creek Formation.

·    Sulphide mineralisation within breccia zones, along stress dilation
fractures, emplaced within pore spaces, voids, or in other rock fractures;
and/or dykes.

 

Main ore minerals observed comprise:

·    Malachite and chrysocolla along foliation, in brecciated/strongly
haematitic sedimentary rocks.

·    Quartzite/rhyolite with chrysocolla on joint surfaces and fractures,
circa 3-5% Cu.

·    Malachite and azurite on joint planes in porous sandstone.

 

For further information, please contact:

 

 Castillo Copper Limited                                             +61 8 6558 0886 
 Dr Dennis Jensen (Australia), Managing Director                      

 Gerrard Hall (UK), Chairman 
                                                                      
 SI Capital Limited (Financial Adviser and Corporate Broker)         +44 (0)1483 413500 
 Nick Emerson                                                          
                                                                       
 Gracechurch Group (Financial PR)                                    +44 (0)20 4582 3500
 Harry Chathli, Alexis Gore, Henry Gamble                             

 

About Castillo Copper

 

Castillo Copper Limited is an Australian-based explorer primarily focused on
copper across Australia and Zambia. The group is embarking on a strategic
transformation to morph into a mid-tier copper group underpinned by its core
projects: 

 

·    A large footprint in the Mt Isa copper-belt district, north-west
Queensland, which delivers significant exploration upside through having
several high-grade targets and a sizeable untested anomaly within its
boundaries in a copper-rich region. 

·    Four high-quality prospective assets across Zambia's copper-belt
which is the second largest copper producer in Africa. 

·    A large tenure footprint proximal to Broken Hill's world-class
deposit that is prospective for zinc-silver-lead-copper-gold and platinoids.
 

·    Cangai Copper Mine in northern New South Wales, which is one of
Australia's highest grading historic copper mines. 

 

The group is listed on the LSE and ASX under the ticker "CCZ." 

 

Competent Person's Statement

The information in this report that relates to Exploration Results and Mineral
Resource Estimates for "BHA Project, East Zone" is based on information
compiled or reviewed by Mr Mark Biggs.  Mr Biggs is a director of ROM
Resources, a company which is a shareholder of Castillo Copper Limited.  ROM
Resources provides ad hoc geological consultancy services to Castillo Copper
Limited.  Mr Biggs is a member of the Australian Institute of Mining and
Metallurgy (member #107188) and has sufficient experience of relevance to the
styles of mineralisation and types of deposits under consideration, and to the
activities undertaken, to qualify as a Competent Person as defined in the 2012
Edition of the Joint Ore Reserves Committee (JORC) Australasian Code for
Reporting of Exploration Results, and Mineral Resources. Mr Biggs holds an
AusIMM Online Course Certificate in 2012 JORC Code Reporting.  Mr Biggs also
consents to the inclusion in this report of the matters based on information
in the form and context in which it appears.

References

 

1)        CCZ ASX Release - 28 February 2022

2)        CCZ ASX Release - 7 September 2020

3)        CCZ ASX Release - 10 August 2021 & 17 November 2021; 28
January 2022

4)        Smith P., 2019, Ayra Mt Oxide prospect, unpublished report by
Yoda Consulting Pty Ltd to Castillo Copper Limited, Apr 2019, 15pp.

APPENDIX A: NWQ COPPER PROJECT
FIGURE A1: PROSPECTS WITHIN NWQ COPPER PROSPECT

 

Source: CCZ geology team

APPENDIX B: ARYA PROSPECT - METALLURGICAL TESTS

Background petrographic description

One composite sample from drill-hole AR_002RC, sized into 7 fractions, was
submitted for optical investigation, with the main aim of characterising the
presence and mode of occurrence of graphite (Schulz and others 2022; refer to
Appendix C for reference list).

 

Polished blocks were prepared for all size fractions, and these were examined
using a petrographic microscope (reflected light). Further, representative
splits of the +800 µm and +500 µm fractions were examined using a stereo
microscope.

 

Reflected light images of selected fields of the polished blocks (all size
fractions) and stereo-microscope images of the unmounted +800 µm and +500 µm
fractions were included in the metallurgical report (refer Appendix C: Schulz
and others 2022). Figure AB-1 illustrates the nature of mica and sulphide
inclusions in the sized schist chips.

 

FIGURE AB-1: PHOTOMICROGRAPH - SCHIST PARTICLES W/MICA & SULPHIDE
INCLUSIONS

Source: ALS Perth

 

The presence of graphite was confirmed by the optical investigation. With the
chosen settings, graphite particles are identified as creamy white, elongated
particles under reflected light. The graphite flakes range in size from a few
µm (not positively identifiable by the optical investigation) to about 50 µm
in length.

 

They occur as fine-grained flakes within larger, silicate-rich particles (see
Figure AB-2 for an example of the graphite grains).

 

FIGURE AB-2: GRAPHITE AND SULPHIDE INCLUSIONS WITHIN SCHIST FRAGMENTS

Source: ALS Perth

 

Graphite sizing and optical analysis

The composite sample supplied to ALS Perth's laboratory was made up as
follows:

·   AR_002RC: 17m - samples CCZ03231 (73m) to CCZ03247 (90m) from the
coarsest fraction saved. This graphite prospect is low grade, but there are
large thicknesses (e.g., 56m @ 1.35% TGC and 0.25 g/t Ag in one hole). The
field association of the Ag and its relationship to graphite has yet to be
resolved. The sulphur and vanadium reporting from assays over the graphite
horizons are low.

·   The sizing of the supplied RC chips and subsequent testing and optical
analysis is given by Figure AB-3 below. No further sizing was conducted on the
graphite component.

FIGURE AB-3: AR_002RC SIZING AND OPTICAL ANALYSIS

Note:

1.        This sizing distribution is for the whole RC chip composite,
not the graphite component.

2.        No graphite grains above 50µm in length were detected.

Source: ALS Perth

APPENDIX C: JORC CODE, 2012 EDITION - TABLE 1 AYRA DRILLING AND SURFACE ROCK CHIP SAMPLING

Section 1 Sampling Techniques and Data

(Criteria in this section apply to all succeeding sections.)

 Criteria                                                 JORC Code explanation                                                            Commentary
 Sampling techniques                                      ·      Nature and quality of sampling (e.g., cut channels, random chips,         Drilling
                                                          or specific specialised industry standard measurement tools appropriate to the

                                                          minerals under investigation, such as down hole gamma sondes, or handheld XRF    ·      Reverse Circulation samples were taken off a cyclone for every
                                                          instruments, etc). These examples should not be taken as limiting the broad      metre drilled, put through a three tier, 87.5/12.5 splitter where
                                                          meaning of sampling.                                                             approximately 2.5 kg of RC chip samples were collected for every metre

                                                                                drilled.  The remainder was bagged separately and stored in case additional
                                                          ·      Include reference to measures taken to ensure sample                      sub sampling is required before the end of the program.
                                                          representivity and the appropriate calibration of any measurement tools or

                                                          systems used.                                                                    ·      Samples were also composited every four metres where visual

                                                                                inspection did not initially indicate copper or cobalt mineralisation.  All
                                                          ·      Aspects of the determination of mineralisation that are Material          samples were collected to maximise optimal representation for each sample.
                                                          to the Public Report.

                                                                                ·      Each metre sample had an amount removed for washing and cleaning
                                                          ·      In cases where 'industry standard' work has been done this would          and sieving then place into metre allocated chip trays. These chips were
                                                          be relatively simple (e.g., 'reverse circulation drilling was used to obtain 1   logged on site by the rig geologists and those logs have been saved into a
                                                          m samples from which 3 kg was pulverised to produce a 30 g charge for fire       spreadsheet and stored on the Company server. Any visible mineralisation,
                                                          assay'). In other cases, more explanation may be required, such as where there   alteration or other salient features were recorded in the logs. Industry-wide,
                                                          is coarse gold that has inherent sampling problems. Unusual commodities or       acceptable, standard practices were adhered to for the drilling and sampling
                                                          mineralisation types (e.g., submarine nodules) may warrant disclosure of         of each metre as per the drilling and sampling Procedures set out before
                                                          detailed information.                                                            commencement of the drilling programme.

                                                                                                                                           Rock Chip Sampling

                                                                                                                                           ·      CCZ completed rock chip sampling methods over at least four (4)
                                                                                                                                           separate surface sampling campaigns and are described in the October and
                                                                                                                                           November 2021 ASX Releases, a generalised description of rock chip sample
                                                                                                                                           collection is presented here.

                                                                                                                                           ·      Rock Chip Samples - were collected up to approximately a 5m
                                                                                                                                           radius around the recorded co-ordinate location. The rock chip fragments that
                                                                                                                                           were collected to make up the sample included a typical fragment size that
                                                                                                                                           approximately ranged from 2-5cm.

                                                                                                                                           ·      Sub-sampling occurred as described in the section 'Sub-sampling
                                                                                                                                           techniques and sample preparation' in Section 1 of the current Table 1.

                                                                                                                                           ·      The surface sample results described in this ASX Release are
                                                                                                                                           suitable for the reporting 'exploration results' for mineral prospectivity,
                                                                                                                                           additional exploration work would have to be completed to geologically model
                                                                                                                                           and then estimate a mineral resource.
 Drilling techniques                                      ·      Drill type (eg core, reverse circulation, open-hole hammer,               ·      Arya. Reverse Circulation, RC, and Rotary Air blast (RAB)
                                                          rotary air blast, auger, Bangka, sonic, etc) and details (eg core diameter,      drilling techniques were utilised for all holes drilled at the Arya Deposit.
                                                          triple or standard tube, depth of diamond tails, face-sampling bit or other
                                                          type, whether core is oriented and if so, by what method, etc).
 Drill sample recovery                                    ·      Method of recording and assessing core and chip sample recoveries         ·      For the 2021 program, within acceptable industry standard limits,
                                                          and results assessed.                                                            all samples collected were of near equal mass and recoveries were also within

                                                                                acceptable limits for RC drilling and all recorded in the daily logs.  Every
                                                          ·      Measures taken to maximise sample recovery and ensure                     effort was made on site to maximise recovery including cleaning out the sample
                                                          representative nature of the samples.                                            trays, splitter and cyclone and ensuring that the drillers progressed at a

                                                                                steady constant rate for the rig to easily complete each metre effectively.
                                                          ·      Whether a relationship exists between sample recovery and grade
                                                          and whether sample bias may have occurred due to preferential loss/gain of
                                                          fine/coarse material.
 Logging                                                  ·      Whether core and chip samples have been geologically and                  ·      Every metre drilled and sampled was logged geologically in
                                                          geotechnically logged to a level of detail to support appropriate Mineral        accordance with industry-wide acceptable standard for RC logging and the
                                                          Resource estimation, mining studies and metallurgical studies.                   logging was qualitative in nature with every metre logged.  The 2021 program

                                                                                recorded visible sulphide, carbonate, and graphite concentrations and
                                                          ·      Whether logging is qualitative or quantitative in nature. Core            alteration minerals, such as orthoclase, epidote, chlorite, and sericite.
                                                          (or costean, channel, etc) photography.

                                                          ·      The total length and percentage of the relevant intersections
                                                          logged.
 Sub-sampling techniques and sample preparation           ·      If core, whether cut or sawn and whether quarter, half or all             Drilling
                                                          core taken.

                                                                                ·      For the 2021 program, samples with pXRF copper <200ppm will be
                                                          ·      If non-core, whether riffled, tube sampled, rotary split, etc.            composited every four metres and all samples were collected to maximise
                                                          and whether sampled wet or dry.                                                  optimal representation for each sample.  If XRF is not available, then all

                                                                                samples with no visible mineralisation were sampled as above.
                                                          ·      For all sample types, the nature, quality, and appropriateness of

                                                          the sample preparation technique.                                                ·      Each metre sample had an amount removed for washing and cleaning

                                                                                and sieving then place into metre allocated chip trays. These chips were
                                                          ·      Quality control procedures adopted for all sub-sampling stages to         logged on site by the rig geologists and those logs have been saved into a
                                                          maximise representivity of samples.                                              spreadsheet and stored on the Company server. Any visible mineralisation,

                                                                                alteration or other salient features were recorded in the logs. Industry wide,
                                                          ·      Measures taken to ensure that the sampling is representative of           acceptable, standard practices were adhered to for the drilling and sampling
                                                          the in-situ material collected, including for instance results for field         of each metre as per the Drilling and Sampling Procedures set out before
                                                          duplicate/second-half sampling.                                                  commencement of the drilling programme.

                                                          ·      Whether sample sizes are appropriate to the grain size of the             ·      Any reporting of significant mineralised intervals was on a
                                                          material being sampled.                                                          received apparent thickness x interval calculation (i.e., thickness averaged).

                                                                                                                                           Rock Chip Sampling

                                                                                                                                           ·      All surface samples were collected dry.

                                                                                                                                           ·      The surface sample results described in this ASX Release are
                                                                                                                                           suitable for the reporting 'exploration results' for mineral prospectivity,
                                                                                                                                           additional exploration work would have to be completed to geologically model
                                                                                                                                           and then estimate a mineral resource.
 Quality of assay data and laboratory tests               ·      The nature, quality and appropriateness of the assaying and               ·      CCZ's RC holes were assayed by an independent laboratory, ALS at
                                                          laboratory procedures used and whether the technique is considered partial or    Mt Isa, Townsville, or Brisbane Australia. Methods used were as follows:
                                                          total.

                                                                                o  Gold - by method Au-AA25 30g charge (fire Assay with AAS finish).
                                                          ·      For geophysical tools, spectrometers, handheld XRF instruments,

                                                          etc, the parameters used in determining the analysis including instrument make   o  High gold values within oxide zone/supergene zone may need further testing
                                                          and model, reading times, calibrations factors applied and their derivation,     by method Au-SCR21.
                                                          etc.

                                                                                o  Copper and 32 other - by method ME-MS61 (HF-HN03-HCL04 acid digest, HCL
                                                          ·      Nature of quality control procedures adopted (eg standards,               leach and ICP-AES finish).
                                                          blanks, duplicates, external laboratory checks) and whether acceptable levels

                                                          of accuracy (ie lack of bias) and precision have been established.               o  Over-limit copper (>10,000 ppm  0.01% ) to be re assayed for copper by
                                                                                                                                           method Cu-OC62 (HF-HN03-HCL04 acid digest, HCL leach and ICP-AES finish).

                                                                                                                                           ·      These analytical methods are considered as suitable and
                                                                                                                                           appropriate for this type of mineralisation.

                                                                                                                                           For the current drilling program ALS Brisbane will analyse all samples. All
                                                                                                                                           elements except for gold were analysed by method ME-MS61 (41 element testing
                                                                                                                                           via Aqua Regia digest then ICP-AES) and with any copper assays >1%, the
                                                                                                                                           copper will be redone using method Cu-OG46 with ICP-AES.  The gold was done
                                                                                                                                           by method AA25.  All methods used were both suitable and appropriate for the
                                                                                                                                           styles of mineralisation present in the Big One Deposit at the time of
                                                                                                                                           sampling.
 Verification of sampling and assaying                    ·      The verification of significant intersections by either                   ·      All CCZ's RC hole samples have been audited for completeness from
                                                          independent or alternative company personnel.                                    ALS have been reviewed by two independent consultant geologists.

                                                          ·      The use of twinned holes.                                                 ·      For current the rock chip sampling, Independent Laboratory

                                                                                assaying by ALS has confirmed, within acceptable limits, the occurrences of
                                                          ·      Documentation of primary data, data entry procedures, data                high-grade copper inferred from the initial XRF readings.  Laboratory
                                                          verification, data storage (physical and electronic) protocols.                  standards and duplicates were used in accordance with standard procedures for

                                                                                geochemical assaying.
                                                          ·      Discuss any adjustment to assay data.
 Location of data points                                  ·      Accuracy and quality of surveys used to locate drill holes                ·      For rock chip samples positions were recorded by handheld GPS
                                                          (collar and down-hole surveys), trenches, mine workings and other locations      with areas highlighting anomalies sometimes returned to for additional
                                                          used in Mineral Resource estimation.                                             sampling and locations checked by handheld GPS.

                                                          ·      Specification of the grid system used.                                    ·      Locational data for the 4 drillholes completed. Collars are

                                                                                listed in MGA94 Zone 54 Easting (mE) and Northing (mN); refer to Table AC-1
                                                          ·      Quality and adequacy of topographic control.                              below.

                                                                                                                                           ·      The Arya rock chip sample dataset is anticipated on average to
                                                                                                                                           have up to a +/-20m horizontal level of accuracy in sample locations and range
                                                                                                                                           up to a +/-10m of accuracy in sample locations for vertical accuracy.

                                                                                                                                           Surface sample and assay data had been prepared and compiled into Manifold GIS
                                                                                                                                           System and all data converted to GDA94-Zone 54.
 Data spacing and distribution                            ·      Data spacing for reporting of Exploration Results.                        ·      For the Arya surface sampling modelling for copper, the average

                                                                                RMS sample-to-sample spacing was as follows:
                                                          ·      Whether the data spacing, and distribution is sufficient to

                                                          establish the degree of geological and grade continuity appropriate for the      o  Rock chip 200m
                                                          Mineral Resource and Ore Reserve estimation procedure(s) and classifications

                                                          applied.                                                                         ·      Drillholes were spaced approximately 250m apart.

                                                          ·      Whether sample compositing has been applied.
 Orientation of data in relation to geological structure  ·      Whether the orientation of sampling achieves unbiased sampling of         ·      In general, the strike of the Surprise Creek Formation is
                                                          possible structures and the extent to which this is known, considering the       east-northeast to east, dipping moderately to the north.
                                                          deposit type.

                                                                                ·      For 'Arya' rock chips there was no fixed orientation as these
                                                          ·      If the relationship between the drilling orientation and the              methods were used in the first instance to define distinct areas of
                                                          orientation of key mineralised structures is considered to have introduced a     anomalisms, based on areas of observed surface mineralisation.
                                                          sampling bias, this should be assessed and reported if material.

                                                                                                                                           ·      For 'Arya' rock chips that produced significant anomalous values
                                                                                                                                           appear to be associated with the mapped fault, fault bounded breccia, and the
                                                                                                                                           Surprise Creek Formation 'PLrd' rock unit ('Prd' historical) that dominates
                                                                                                                                           the 'Arya' prospect to the south of the fault.

                                                                                                                                           ·      All drilling is intended to be vertical to intersect the dipping
                                                                                                                                           sedimentary beds.
 Sample security                                          ·      The measures taken to ensure sample security.                             ·      Each day's RC samples were removed from site and stored in a
                                                                                                                                           secure location off site.

                                                                                                                                           ·      The RC chip samples taken were securely locked within the vehicle
                                                                                                                                           on site until delivered to Mt Isa for despatch to the laboratory in person by
                                                                                                                                           the field personnel.
 Audits or reviews                                        ·      The results of any audits or reviews of sampling techniques and           No external reviews or audits have been undertaken, except for the Independent
                                                          data.                                                                            Geologists Report by SRK in 2019 for the LSE Listing and a review of the
                                                                                                                                           airborne and ground geophysics by the GeoDiscovery Group.  Note, the
                                                                                                                                           reference is: Nelson K., Review of open file EM and magnetic geophysical data
                                                                                                                                           at Arya Prospect, GeoDiscovery Group, unpublished confidential report to
                                                                                                                                           Castillo Copper Limited, June 2021, 16pp.

 

 

Drilling program summary

The inaugural drilling campaign at the Arya Prospect (Figure AC-1) was
completed in December 2021, after a massive logistical effort to prepare the
drill-pads and heli-lift the rig and all supporting equipment to site (see
Figure AC-2).  In each hole thick horizons (up to 55m) of dark grey and black
carbonaceous siltstone / schist were intersected (Figure AC-3), with
scattered, sparse base-metal sulphides, low levels of silver and TREO (to
400ppm), and fine-grained graphite mineralisation occurrences which remains
open in all directions and to depth.

 

FIGURE AC-1: PROSPECTS COMPRISING THE NWQ COPPER PROJECT

Source: CCZ geology team

FIGURE AC-2: DRILLING AT SITE AR_20 (AR_001RCR)

Location:  351825 mN; 7865551 Mn; Source: CCZ geology team

The "proof of concept" campaign, which eventually only comprised five initial
RC drill-holes at four sites.  Delays to the drilling were extensive and have
included:

·    Wet weather and flooding.

·    Daytime temperatures >43 degrees Celsius.

·    Compressor overheating.

·    Drill thread breaking.

·    Large water flows in each hole drilled.

·    Bushfires.

·    Helicopter lifts of all gear required between sites and daily travel
to/from site.

·    Very hard quartzite wearing down hammer components.

The key focus was drill-testing the three targets identified by BHP in the
mid-1990s including EG01, EG02 and EG10.  Of these, EG01 had been interpreted
to potentially be a massive sulphide bedrock conductor 130m thick, 1,500m long
and 450m wide at a revised 100-200m depth.

Drilling to date has found no sign of massive copper sulphide mineralisation,
but instead thick horizons (10-40m) of a dark grey to black carbonaceous,
siltstone to schist, exhibiting scattered base metal mineralisation and
fine-grained graphite occurrences (Figure AC-3).  The horizons are not
magnetic, but portable XRF readings, supported by laboratory analyses have
identified scattered anomalous chromium, zinc, cobalt, manganese, and rare
earth element readings throughout the sequence (Figure AC-4).  All 1m samples
were collated to 4m composites, then analysed for a comprehensive suite of
trace and rare earth elements, total carbon, and total graphitic carbon.

FIGURE AC-3:  AR_001RCR CHIP TRAY 111-120m

Source: CCZ geology team

Post reconciling historic geochemical and geophysical data, the Board decided
it was strategically more prudent to orchestrate a "proof of concept" reduced
campaign comprising five RC drill-holes initially which included sites AR04,
AR08, AR09, AR13 & AR21 (Table AC-1 and Figure AC-4).  Vertical holes
were planned however due to the drilling techniques and narrower diameter pipe
employed, several completed drillholes exhibited significant downhole
deviations to the south-east and south-west (Figure AC-5).

The exploration program objective was changed so that if the first-round
observations and geological findings were encouraging, there is built-in
flexibility to expand the campaign to fully drill-test the extent of any
underlying system.

Drilling of AR_002RC progressed to a depth of 238m before the drill string
disintegrated leaving most of the drill string stuck in the hole.  The
drillhole had deviated significantly, being almost horizontal at total
depth.  Drilling in AR_001RCR through to AR_004RC intersected, hard, dark,
material identified as a carbonaceous schist (See Appendix B).  The material
contains no base metal mineralisation, but a low tenor of rare earth elements
(to 400ppm TREO) and graphite (0.5 - 2%; refer to Appendix B) that was
confirmed by laboratory testing.

TABLE AC-1:  DRILLHOLE LOCATION

 Drillhole  Easting  Northing  AHD    Total Depth  Azimuth  Dip  Type    Comments
 AR_001RC   351793   7865526   202.2  96           175      -85  RC      Quartzite to 42m, dark carbonaceous schist to 90m; Major fault @90m.
 AR_001RCR  351825   7865551   203.4  142          172      -60  RC/PCD  Quartzite then dark carbonaceous siltstones and schists to TD
 AR_002RC   352735   7865605   191.8  238          170      -17  RC      Quartzite then dark carbonaceous siltstones and schists to TD
 AR_003RC   352971   7865433   192.5  143          203      -60  RC      Quartzite then dark carbonaceous siltstones and schists to TD
 AR_004RC   353486   7865310   188    177          160      -67  RC      Quartzite then dark carbonaceous siltstones and schists to TD

Notes: Coordinate system is MGA94-Zone 54, collars are AHD.

 

Section 2 Reporting of Exploration Results

(Criteria listed in the preceding section also apply to this section.)

 Criteria                                                          JORC Code explanation                                                            Commentary
 Mineral tenement and land tenure status                           ·      Type, reference name/number, location and ownership including             ·      The following mineral tenures are held 100% by subsidiaries of
                                                                   agreements or material issues with third parties such as joint ventures,         Castillo Copper Limited, totalling an area of approximately 961km(2) in the
                                                                   partnerships, overriding royalties, native title interests, historical sites,    "NWQ project":
                                                                   wilderness or national park and environmental settings.

                                                                                ·      EPM 26574 (Valparaisa North) - encompasses the Big One historical
                                                                   ·      The security of the tenure held at the time of reporting along            mineral resource, Holder Total Minerals Pty Ltd, granted 12-June-2018 for a
                                                                   with any known impediments to obtaining a licence to operate in the area.        5-year period over 100 sub-blocks (323.3Km2), Expires 11-June-2023.

                                                                                                                                                    ·      EPM 26462 (Big Oxide North) - encompasses the 'Boomerang'
                                                                                                                                                    historical mine and the 'Big One' historical mine, Holder: QLD Commodities Pty
                                                                                                                                                    Ltd, granted: 29-Aug-2017 for a 5-year period over 67 sub-blocks (216.5Km(2)),
                                                                                                                                                    Expires: 28-Aug-2022.

                                                                                                                                                    ·      EPM 26525 (Hill of Grace) - encompasses the Arya significant
                                                                                                                                                    aeromagnetic anomaly, Holder: Total Minerals Pty Ltd for a 5-year period over
                                                                                                                                                    38 sub-blocks (128.8Km2), Granted: 12-June 2018, Expires: 11-June-2023.

                                                                                                                                                    ·      EPM 26513 (Torpedo Creek/Alpha Project) - Granted 13-Aug 2018 for
                                                                                                                                                    a 5-year period over 23 sub-blocks (74.2Km2), Expires 12-Aug-2023; and

                                                                                                                                                    ·      EPM 27440 (The Wall) - An application was lodged on the
                                                                                                                                                    12-Dec2019 over 70 sub-blocks (~215Km(2)) by Castillo Copper Limited. The
                                                                                                                                                    tenure was granted on the 7(th) of March 2021.
 Exploration done by other parties                                 ·      Acknowledgment and appraisal of exploration by other parties.             ·      A selection of historical QDEX / mineral exploration reports has
                                                                                                                                                    been reviewed for historical tenures that cover or partially cover the Project
                                                                                                                                                    Area in this announcement. Federal and State Government reports supplement the
                                                                                                                                                    historical mineral exploration reporting (QDEX open file exploration records).

                                                                                                                                                    ·      Most explorers were searching for Cu-Au-U and/or Pb-Zn-Ag, and,
                                                                                                                                                    proving satellite deposit style extensions to the several small sub-economic
                                                                                                                                                    copper deposits (e.g., Big Oxide and Josephine).

                                                                                                                                                    ·      With the NWQ Project in regional proximity to Mt Isa and numerous
                                                                                                                                                    historical and active mines, the Project area has seen the historical mineral
                                                                                                                                                    tenures subject to various styles of surface sampling, with selected locations
                                                                                                                                                    typically targeted at specific locations within the NWQ Pillar by shallow
                                                                                                                                                    drilling (Total hole depth is typically less than 75m).

                                                                                                                                                    ·      The NWQ project tenure package has a significant opportunity to
                                                                                                                                                    be reviewed and explored by modern exploration methods in a coherent package
                                                                                                                                                    of EPM's, with three of these forming a contiguous tenure package.

                                                                                                                                                    Arya prospect - the five (5) historical exploration reports generated by
                                                                                                                                                    various explorers that contributed information and data to this ASX Release
                                                                                                                                                    are detailed in the References section of the main body.
 Geology                                                           ·      Deposit type, geological setting, and style of mineralisation.            ·      The NWQ project is located within the Mt Isa Inlier of western
                                                                                                                                                    Queensland, a large, exposed section of Proterozoic (2.5 billion- to
                                                                                                                                                    540-million-year-old) crustal rocks. The inlier records a long history of
                                                                                                                                                    tectonic evolution, now thought to be like that of the Broken Hill Block in
                                                                                                                                                    western New South Wales.

                                                                                                                                                    ·      The NWQ project lies within the Mt Oxide Domain, straddling the
                                                                                                                                                    Lawn Hill Platform and Leichhardt River Fault Trough. The geology of the
                                                                                                                                                    tenement is principally comprised of rocks of the Surprise Creek and Quilalar
                                                                                                                                                    Formations which include feldspathic quartzites, conglomerates, arkosic grits,
                                                                                                                                                    shales, siltstones and minor dolomites and limestones.

                                                                                                                                                    ·      The NWQ Pillar project area is cut by a major fault zone,
                                                                                                                                                    trending north-northeast to south-southwest across the permits. This fault is
                                                                                                                                                    associated with major folding, forming several tight syncline and anticline
                                                                                                                                                    structures along its length.

                                                                                                                                                    ·      The desktop studies commissioned by CCZ on the granted mineral
                                                                                                                                                    tenures described four main styles of mineralisation account for most mineral
                                                                                                                                                    resources within the rocks of the Mt Isa Province (after Withnall &
                                                                                                                                                    Cranfield, 2013).

                                                                                                                                                    ·      Sediment hosted silver-lead-zinc - occurs mainly within fine
                                                                                                                                                    grained sedimentary rocks of the Isa Super basin within the

                                                                                                                                                    ·      Western Fold Belt. Deposits include Black Star (Mount Isa PbZn),
                                                                                                                                                    Century, George Fisher North, George Fisher South (Hilton) and Lady Loretta
                                                                                                                                                    deposits.

                                                                                                                                                    ·      Brecciated sediment hosted copper - occurs dominantly within the
                                                                                                                                                    Leichhardt, Calvert, and Isa Super basin of the Western Fold Belt, hosted in
                                                                                                                                                    brecciated dolomitic, carbonaceous, and pyritic sediments or brecciated rocks
                                                                                                                                                    proximal to major fault/shear zones. Includes the Mount Isa copper orebodies
                                                                                                                                                    and the Esperanza/Mammoth mineralisation.

                                                                                                                                                    ·      Iron-oxide-copper-gold ("IOCG") - predominantly chalcopyrite,
                                                                                                                                                    pyrite magnetite/hematite mineralisation within high grade metamorphic rocks
                                                                                                                                                    of the Eastern Fold Belt. Deposits of this style include Ernest Henry,
                                                                                                                                                    Osborne, and Selwyn; and

                                                                                                                                                    ·      Broken Hill type silver-lead-zinc - occur within the high-grade
                                                                                                                                                    metamorphic rocks of the Eastern Fold Belt. Cannington is the major example,
                                                                                                                                                    but several smaller currently sub-economic deposits are known.

                                                                                                                                                    ·      Gold is primarily found associated with copper within the IOCG
                                                                                                                                                    deposits of the Eastern Fold Belt. However, a significant exception is noted
                                                                                                                                                    at Tick Hill where high grade gold mineralisation was produced, between 1991
                                                                                                                                                    and 1995 by Carpentaria Gold Pty Ltd, some 700 000 tonnes of ore was mined at
                                                                                                                                                    an average grade of 22.5 g/t Au, producing 15 900 kg Au. The Tick Hill deposit
                                                                                                                                                    style is poorly understood (Withnall & Cranfield, 2013).

                                                                                                                                                    ·      ROM Resources had noted in a series of recent reports for CCZ on
                                                                                                                                                    the granted tenures, that cover the known mineralisation styles including:

                                                                                                                                                    o  Stratabound copper mineralisation within ferruginous sandstones and
                                                                                                                                                    siltstones of the Surprise Creek Formation.

                                                                                                                                                    o  Disseminated copper associated with trachyte dykes.

                                                                                                                                                    o  Copper-rich iron stones (possible IOCG) in E-W fault zones; and

                                                                                                                                                    o  possible Mississippi Valley Type ("MVT") stockwork sulphide mineralisation
                                                                                                                                                    carrying anomalous copper-lead-zinc and silver.

                                                                                                                                                    ·      The Mt Oxide and Mt Gordon occurrences are thought to be breccia
                                                                                                                                                    and replacement zones with interconnecting faults. The Mt Gordon/Mammoth
                                                                                                                                                    deposit is hosted by brittle quartzites, and Esperanza by carbonaceous shales.
                                                                                                                                                    Mineralisation has been related to the Isan Orogeny (1,590 - 1,500 Ma).

                                                                                                                                                    ·      Mineralisation at all deposits is primarily
                                                                                                                                                    chalcopyrite-pyrite-chalcocite, typically as massive sulphide within breccias.

                                                                                                                                                    ·      At the Big One prospect, West Australian Metals NL described the
                                                                                                                                                    mineralisation as (as sourced from the document "West Australian Metals NL,
                                                                                                                                                    1994. Drill Programme at the "Big One" Copper Deposit, North Queensland for
                                                                                                                                                    West Australian Metals NL."):

                                                                                                                                                    ·      The targeted lode / mineralised dyke is observable on the
                                                                                                                                                    surface. The mineralisation targeted in the 1993 drilling programmed is a
                                                                                                                                                    supergene copper mineralisation that includes malachite, azurite, cuprite, and
                                                                                                                                                    tenorite, all associated with a NE trending fault (062(o) to 242(o)) that is
                                                                                                                                                    intruded by a porphyry dyke.

                                                                                                                                                    ·      The mineralised porphyry dyke is vertical to near vertical
                                                                                                                                                    (85(o)), with the 'true width' dimensions reaching up to 7m at surface. o At
                                                                                                                                                    least 600m in strike length, with strong Malachite staining observed along the
                                                                                                                                                    entire strike length, with historical open pits having targeted approximately
                                                                                                                                                    200m of this strike. Exact depth of mining below the original ground surface
                                                                                                                                                    is not clear in the historical documents, given the pits are not battered it
                                                                                                                                                    is anticipated that excavations have reached 5m to 10m beneath the original
                                                                                                                                                    ground surface.

                                                                                                                                                    ·      Associated with the porphyry dyke are zones of fractured and/or
                                                                                                                                                    sheared rock, the siltstones are described as brecciated, and sandstones
                                                                                                                                                    around the shear as carbonaceous.

                                                                                                                                                    ·      The known mineralisation from the exploration activities to date
                                                                                                                                                    had identified shallow supergene mineralisation, with a few drillholes
                                                                                                                                                    targeting deeper mineralisation in and around the 200m of strike historical
                                                                                                                                                    open A strongly altered hanging wall that contained malachite and cuprite
                                                                                                                                                    nodules. Chalcocite mineralization has been identified but it is unclear on
                                                                                                                                                    the prevalence of the Chalcocite; and the mineralisation was amenable to high
                                                                                                                                                    grade open pit mining methods of the oxide mineralization (as indicated by
                                                                                                                                                    numerous historical open pit shallow workings into the shear zone).

                                                                                                                                                    ·      Desktop studies commissioned by CCZ and completed by ROM
                                                                                                                                                    Resources and SRK Exploration have determined that the Big One prospect is
                                                                                                                                                    prospective for Cuco, and Ag.

                                                                                                                                                    ·      Desktop studies commissioned by CCZ have determined the Boomerang
                                                                                                                                                    prospect contains:

                                                                                                                                                    ·      Secondary copper staining over ~800m of strike length.

                                                                                                                                                    ·      Associated with a major east-west trending fault that juxtaposes
                                                                                                                                                    the upper Surprise Creek Formation sediments against both the underlying Bigie
                                                                                                                                                    Formation and the upper Quilalar Formation units.

                                                                                                                                                    ·      At the 'Flapjack' prospect there is the potential for:

                                                                                                                                                    o  Skarn mineralisation for Cu-Au         and/or    Zn-Pb-Cu from
                                                                                                                                                    replacement carbonate mineralisation, particularly the Quilalar Formation.

                                                                                                                                                    o  Thermal Gold Auroele mineralisation is a potential model due to the high
                                                                                                                                                    silica alteration in thermal aureole with contact of A-Type Weberra Granite -
                                                                                                                                                    related to the Au mineralisation; and/or

                                                                                                                                                    o  IOCG mineralisation related to chloride-rich fluids.

                                                                                                                                                    ·      At the 'Crescent' prospect there is the potential for:

                                                                                                                                                    o  Skarn      mineralisation for Cu-Au and/or Zn-Pb-Cu from replacement
                                                                                                                                                    carbonate mineralisation, particularly the Quilalar Formation; and/or

                                                                                                                                                    o  Thermal Gold Auroele mineralisation is a potential model due to the high
                                                                                                                                                    silica alteration in thermal aureole with contact of A-Type Weberra Granite -
                                                                                                                                                    related to the Au mineralisation; and

                                                                                                                                                    o  IOCG mineralisation related to potassic rich fluids.

                                                                                                                                                    ·      At the 'Arya' prospect there is the potential for:

                                                                                                                                                    o  Supergene mineralisation forming at the surface along the fault, fault
                                                                                                                                                    breccia, and the Surprise Creek Formation 'PLrd' rock unit ('Prd' historical).

                                                                                                                                                    o  Epigenetic replacement mineralisation for Cu (with minor components of
                                                                                                                                                    other base metals and gold) from replacement carbonate mineralisation,
                                                                                                                                                    particularly the Surprise Creek Formation.

                                                                                                                                                    o  Skarn mineralisation for Cu-Au and/or Zn-Pb-Cu from replacement carbonate
                                                                                                                                                    mineralisation, particularly the Surprised Creek Formation; and/or

                                                                                                                                                    o  IOCG mineralisation related to chloride rich fluids.

                                                                                                                                                    A selection of publicly available QDEX documents / historical exploration
                                                                                                                                                    reports have been reviewed, refer to Section 2, sub-section "Further Work" for
                                                                                                                                                    both actions in progress and proposed future actions.
 Drill hole Information                                            ·      A summary of all information material to the understanding of the         ·      There is no historical drilling at Arya.
                                                                   exploration results including a tabulation of the following information for

                                                                   all Material drill holes:                                                        ·      For the 2021 program, all drillhole information was coded to the

                                                                                same formatted spreadsheets used by CCZ, using the LogCheck field software.
                                                                   o  easting and northing of the drill hole collar

                                                                                ·      For CCZ's current drilling program, this information has been
                                                                   o  elevation or RL (Reduced Level - elevation above sea level in metres) of      recorded in formatted spreadsheets during the drilling and will be checked and
                                                                   the drill hole collar                                                            verified at the conclusion of the current program.

                                                                   o  dip and azimuth of the hole                                                   ·      A summary of the holes drilled are given in Table AC-1 in Section

                                                                                1 of Appendix C, above.
                                                                   o  down hole length and interception depth

                                                                   o  hole length.

                                                                   ·      If the exclusion of this information is justified on the basis
                                                                   that the information is not Material and this exclusion does not detract from
                                                                   the understanding of the report, the Competent Person should clearly explain
                                                                   why this is the case.
 Data aggregation methods                                          ·      In reporting Exploration Results, weighting averaging techniques,         ·      No data aggregation methods are utilised in the current ASX
                                                                   maximum and/or minimum grade truncations (e.g. cutting of high grades) and       Release, since the sampling types are surface rock chip samples.
                                                                   cut-off grades are usually Material and should be stated.

                                                                   ·      Where aggregate intercepts incorporate short lengths of
                                                                   high-grade results and longer lengths of low-grade results, the procedure used
                                                                   for such aggregation should be stated and some typical examples of such
                                                                   aggregations should be shown in detail.

                                                                   ·      The assumptions used for any reporting of metal equivalent values
                                                                   should be clearly stated.
 Relationship between mineralisation widths and intercept lengths  ·      These relationships are particularly important in the reporting           ·      The strike of the country rock is northeast to east, with the
                                                                   of Exploration Results.                                                          deep Arya conductor is orientated east - west. The smaller, shallower

                                                                                conductors strike north-northeast to northeast.  The main faulting trends is
                                                                   ·      If the geometry of the mineralisation with respect to the drill           northeast.
                                                                   hole angle is known, its nature should be reported.

                                                                                ·      When available, all mineralised intervals (i.e., >500ppm) will
                                                                   ·      If it is not known and only the down hole lengths are reported,           be reported in future ASX releases as the "as-intersected" apparent thickness
                                                                   there should be a clear statement to this effect (eg 'down hole length, true     (in metres) and given that all drillholes dip at -90 degrees from the
                                                                   width not known').                                                               horizontal, true intersection widths will be calculated during the block
                                                                                                                                                    modelling process.
 Diagrams                                                          ·      Appropriate maps and sections (with scales) and tabulations of            ·      This part will be done once CCZ's current drilling program is
                                                                   intercepts should be included for any significant discovery being reported       completed, and all samples have been assayed and verified.
                                                                   These should include, but not be limited to a plan view of drill hole collar

                                                                   locations and appropriate sectional views.                                       ·      Appropriate diagrams are presented in the body and the Appendices
                                                                                                                                                    of the current ASX Release. Where scales are absent from the diagram, grids
                                                                                                                                                    have been included and clearly labelled to act as a scale for distance.

                                                                                                                                                    ·      Maps and Plans presented in the current ASX Release are in MGA94
                                                                                                                                                    Zone 54, Eastings (mN), and Northing (mN), unless clearly labelled otherwise.
 Balanced reporting                                                ·      Where comprehensive reporting of all Exploration Results is not           ·      Comprehensive reporting was completed (Biggs 2022) once CCZ's
                                                                   practicable, representative reporting of both low and high grades and/or         drilling program had all sample queries returned and have been verified.
                                                                   widths should be practiced to avoid misleading reporting of Exploration

                                                                   Results.                                                                         o  Appropriate diagrams are presented in the body and the Appendices of the
                                                                                                                                                    current ASX Release (see Figure AC-5 and AC-6).  Where scales are absent from
                                                                                                                                                    the diagram, grids have been included and clearly labelled to act as a scale
                                                                                                                                                    for distance.

                                                                                                                                                    ·      A complete comparison of visual mineralisation estimated by the
                                                                                                                                                    site geologist will be published once all assays are returned.  All
                                                                                                                                                    intersected intervals are apparent thicknesses in metres.
 Other substantive exploration data                                ·      Other exploration data, if meaningful and material, should be             GEOTEM & PROTEM:
                                                                   reported including (but not limited to): geological observations; geophysical

                                                                   survey results; geochemical survey results; bulk samples - size and method of    ·      The airborne electromagnetic GEOTEM geophysical survey undertaken
                                                                   treatment; metallurgical test results; bulk density, groundwater, geotechnical   by BHP Minerals in 1997 on historical tenure EPM11383 & EPM1152. A total
                                                                   and rock characteristics; potential deleterious or contaminating substances.     of 726-line kilometres were flown on a SE-NW, flown by 'Geoterrex-Dighem Pty
                                                                                                                                                    Limited' at a mean height of approximately 105m above the ground surface (line
                                                                                                                                                    spacing 500m apart). Previous interpretations the penetration of the GEOTEM
                                                                                                                                                    method to have an estimated range of between 200-300m below the ground
                                                                                                                                                    surface, this is dependent on conductivity contrasts, size, and attitude of
                                                                                                                                                    the subsurface targets. Eleven (11) anomalies were identified, with four (4)
                                                                                                                                                    recommended for follow up, with three (3) of the four (4) anomalies followed
                                                                                                                                                    up by ground geophysical at what CCZ calls the 'Arya' prospect. The BHP
                                                                                                                                                    Minerals 1997 GEOTEM survey information was extracted from QDEX Data to
                                                                                                                                                    accompany the QDEX report information.

                                                                                                                                                    ·      The 'Arya' prospect anomalies are EG01, EG02, EG10, with the
                                                                                                                                                    geophysical observations of the body and Appendices of the current ASX
                                                                                                                                                    Release, including the PROTEM observations. The PROTEM observations are
                                                                                                                                                    anticipated to have a deeper penetration than the GEOTEM observations, based
                                                                                                                                                    on the PROTEM loop, survey traverse, and/or depth sounding method applied.

                                                                                                                                                    QUESTEM & GENIE-EM:

                                                                                                                                                    ·      The airborne electromagnetic GEOTEM geophysical survey undertaken
                                                                                                                                                    by Mount Isa Mines in 1991 on historical tenure EPM7448, EPM7338, and EPM7863.
                                                                                                                                                    A total of approximately 600km-line kilometres (exact line length would need
                                                                                                                                                    to be extracted from digitised images) would were flown on a SE-NW, flown by
                                                                                                                                                    'Aerodata Holdings Limited' at a mean height of approximately 120m above the
                                                                                                                                                    ground surface (line spacing 400m apart). In a previous ASX release (July
                                                                                                                                                    2020) Xplore Resources Pty Ltd interprets the penetration of the QUESTEM
                                                                                                                                                    method to have an estimated range of between 200-300m below the ground
                                                                                                                                                    surface, this is dependent on conductivity contrasts, size, and attitude of
                                                                                                                                                    the subsurface targets. Twentynine (29) anomalies were identified across the
                                                                                                                                                    three (3) historical tenure, with six (6) recommended for follow up ground
                                                                                                                                                    geophysical survey for historical tenure EPM7448, and one of these L4 near the
                                                                                                                                                    Arya prospect.

                                                                                                                                                    ·      Arya prospect anomaly L4 followed up by a ground electromagnetic
                                                                                                                                                    traverse by Mount Isa Mines GENIE-EM is to the west of the EG02 BHP minerals
                                                                                                                                                    anomaly.

                                                                                                                                                    ·      Queensland Government Data: 'PLrd' rock unit lower boundary from
                                                                                                                                                    the Surprise Creek Formation sourced from QSpatial and aligns with GeoResGlobe
                                                                                                                                                    - this is equivalent to the historical tenure reports 'Prd' rock unit lower
                                                                                                                                                    boundary from the Surprise Creek Formation.

                                                                                                                                                    GEODISCOVERY REVIEW

                                                                                                                                                    The study of Nelson (2021) concluded that:

                                                                                                                                                    ·      Whilst hard copies of the 1997 BHP ground EM data are available,
                                                                                                                                                    no digital data is on open file. Hard copy profiles have been visually
                                                                                                                                                    interpreted, however due to lack of digital data it cannot be remodelled.
                                                                                                                                                    The historic BHP model results and survey locations have not been provided and
                                                                                                                                                    there is uncertainty in the location of Anomaly E02.

                                                                                                                                                    ·      Magnetic modelling, CDI and LEI of the TEMPEST survey line
                                                                                                                                                    indicate the BHP depth estimate of conductive from the EG01 sounding is likely
                                                                                                                                                    over estimated.  Depth to main conductive sources appears to be between
                                                                                                                                                    around 200m beneath surface (Nelson (2021).

                                                                                                                                                    ·      EG02 appears to be associated with a fault and EG10 appears to be
                                                                                                                                                    more surficial.

                                                                                                                                                    ·      It is recommended that the LEI of the TEMPEST survey (most recent
                                                                                                                                                    AEM data acquired in the region), along with magnetic model output be used to
                                                                                                                                                    plan the next drill campaign.  The current drill plan could be improved to
                                                                                                                                                    better test the modelled conductive sources and structural features.

                                                                                                                                                    ·      If the drill testing of the conductive sources indicates the
                                                                                                                                                    presence of prospective lithologies and/or mineralisation, then consideration
                                                                                                                                                    should be given to acquiring detailed ground EM and magnetic coverage to
                                                                                                                                                    further assist targeting.
 Further work                                                      ·      The nature and scale of planned further work (eg tests for                ·      Further work will consist of a combination of:
                                                                   lateral extensions or depth extensions or large-scale step-out drilling).

                                                                                o  Fourteen (14) hole RC drilling Program
                                                                   ·      Diagrams clearly highlighting the areas of possible extensions,

                                                                   including the main geological interpretations and future drilling areas,         o  Soil and or Rock chip sampling
                                                                   provided this information is not commercially sensitive.

                                                                                                                                                    o  Ground IP or EM Survey

 

 

FIGURE AC-4:  ARYA DRILLHOLE LOCATION vs EM ANOMALY

Notes:

1.        Coordinate system is MGA94-Zone 54, collars are AHD.

2.        Shows EM anomalies, MIM EM airborne survey, Location of
AusAEM survey line 2024_003, and the "as drilled" 2021 collars.

FIGURE AC-5: ARYA DRILLHOLE LOCATION AND GRAPHITE INTERSECTIONS

Notes:

1.        View at Ayra looking north-east, showing topography (2m
contours) and drilling.

2.        Coloured bars represent Cg >0.5%, with purple higher grade
(>1% TGC).

3.        Light green polygons (see Figure AC-4) present surface copper
anomalies (>250ppm Cu) untested by drilling.

4.        Source: CCZ Geology Team.

 

References

Anaconda Australia Inc., 1971. Authority to Prospect 791M "Myally",
Queensland. Final Report. QDEX Report number: 3544.

Biggs M.S., 2021, EPM 26525 Hill of Grace - 2021 Arya Drilling and Exploration
Program, End of Hitch Report - Drilling, Assay, and Metallurgical Testing
Completed, July 2022, unpublished report by ROM Resources for Castillo Copper
Limited.

BHP Minerals Pty Ltd, 1997. EPM 11383 (Alsace Camp), 11452 (Epsilon), Combined
Annual Report for the Period Ending 19/12/97. QDEX Report number: 29762.

BHP Minerals Pty Ltd, 1998. EPM 11383 (Alsace Camp), 11452 (Epsilon), Combined
Annual/Final Report for the Period Ending 19/12/98. QDEX Report number: 30750

CCZ ASX Release - 28 April 2020.

CRA Exploration Pty Limited, 1995. Exploration Report for Minerals No. 9575
"Epsilon", Queensland. Annual Report for the period ended August 3, 1995. QDEX
Report number: 27102.

CRA Exploration Pty Limited, 1996. Exploration Report for Minerals No. 9575
"Epsilon", Queensland. Third Annual and Final Report for the Period Ending 2
July 1996. QDEX Report number: 28337

GeoResGlobe, 2021, Detailed Geology 1:100,000 layers.
https://georesglobe.information.qld.gov.au/ Accessed 2021-Jun-21.

M.I.M Exploration Pty Ltd, 1992a, Exploration Permit for Minerals No. 7863
"Eldorado" Queensland. Annual Report for the 12 months ended April 17, 1992.
QDEX Report number: 23661.

M.I.M Exploration Pty Ltd, 1992b "Myally Creek" EPM 7338 and "Lagoon Creek"
EPM 7448 Joint Twelve Month Report for Period 18 May 1990 to 18 May 1991
Queensland, Australia. QDEX Report number: 23516.

Mt Isa Metals Ltd, 2010. EPM 15767, Myally Tenement, Annual Report for the
Period 5/06/2009 to 4/6/2010. QDEX Report number: 64491.

M.I.M Exploration Pty Ltd, 1993. Exploration Permit for Minerals Nos. 7448
"Lagoon Creek". Second Annual Report 18 May 1991 to 17 May 1992, Queensland
Australia. QDEX Report number: 24523.

Nelson K., 2021, Review of open file EM and magnetic geophysical data at Arya
Prospect, GeoDiscovery Group, unpublished confidential report to Castillo
Copper Limited, June 2021, 16pp

Pacminex Pty Limited, 1975, Authority to Prospect No. 1494M "Alsace Area",
Queensland. Annual Report. QDEX Report number: 5602.

Queensland Government, 2021. Queensland Geology Detailed Web Map Service:
http://qldspatial.information.qld.gov.au/catalogue/custom/search.page?q=solid+geology#

Schulz, M., Liu, J., and de Nooy, D., 2022, MIN5684 (A23397), Castillo Copper
Ltd, Graphite Optical Analysis, ALS Metallurgical Services, May 2022, 18pp

Valenta, R., 2018. NW Queensland Mineral Province Deposit Atlas Prototype
Report - the Mount Isa and Ernest Henry Deposits. DNRME-GSQ Commissioned study
and report.

 

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